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侯天寶 發問於 科學及數學化學 · 1 十年前

焰色試驗一問?

求 Pb2+ 、 Hg+ 和 Cr3+ 的焰色試驗結果

2 個解答

評分
  • Carson
    Lv 6
    1 十年前
    最愛解答

    Flame Coloration by Element

    lead blue/white

    mercury blue-green (not very decisive)

    The borax bead test is a traditional part of qualitative inorganic analysis to test for the presence of certain metals.

    A small loop is made in the end of a platinum wire (as used in the flame test) and heated in a Bunsen flame until red hot. It is then dipped into powdered borax, and the adhering solid is held in the hottest part of the flame where it swells up as it loses its water of crystallization and then shrinks, forming a colourless, transparent glass-like bead (a mixture of sodium metaborate and boric anhydride),

    The bead is moistened and dipped into the sample to be tested such that only a tiny amount of the substance adheres to the bead. If too much substance is used, the bead will become dark and opaque. The bead and adhering substance is then heated in the lower, reducing, part of the flame, allowed to cool, and the colour observed. It is then heated in the upper, oxidising, part of the flame, allowed to cool, and the colour observed again.

    Characteristic coloured beads are produced with salts of copper, iron, chromium, manganese, cobalt and nickel. After the test, the bead is removed by heating it to fusion point, and jerking it into a vessel of water.

    Chromium (Cr)

    Reducing flame

    Green, hot and cold

    Oxidising flame

    Dark yellow when hot; green when cold

    I hope this can help your understanding. =)

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